以技术的工程应用、解决实际环境问题为导向,专注水质净化原理、技术和应用研究。
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水质与水生态研究中心
兰华春
邮箱:hclan@tsinghua.edu.cn
电话:010-62790105
地点:清华大学伟清楼405,100084
研究兴趣
主要研究方向
(1)吸附技术。针对低浓度重金属及贵金属,研究吸附与回收的过程机制及工程应用。
(2)分离技术。针对难降解有机物、重金属离子等,研究以膜分离技术为核心的过程机制及工程应用。
(3)电化学技术。重点研究电催化氧化、电催化还原、电氧化-还原协同的原理、技术及其在有机物降解及高价重金属去除等方面的工程应用。
教育背景
2009/03-2013/07 中国科学院大学 环境工程 博士
2003/09-2006/03 福州大学 环境工程 硕士
1999/09-2003/07 昆明理工大学 环境科学 学士
工作履历
2017/08-至今 清华大学环境学院 长聘副教授/特别研究员
2006/06-2017/07 中国科学院生态环境研究中心 研实员/助研/副研
研究概况
主要主持课题
1. 项目名称:国家自然科学基金委面上项目—“电控吸附膜的研制及其对弱极性微量有机污染物的去除机制”;项目编号:52170003,起止时间:2021/01-2024/12
2. 项目名称:国家自然科学基金委面上项目—“电控自清洁g-c3n4疏松纳滤膜研制及其净水机制”;项目编号:51978373,起止时间:2020/01-2023/12
3. 课题名称:厂村融合复合面源污染控制技术集成及示范;课题编号:20181820211;课题类别:国家科技重大专项;起止日期:2017/01-2020/12
4. 项目名称:国家优秀科学基金项目—“水污染控制”;项目编号:51722811;起止时间:2018/01-2020/12
5. 项目名称:国家自然科学基金委面上项目—“间接电还原净水过程的原子氢产生与作用机制”;项目编号:51478455,起止时间:2015/01-2018/12
6. 项目名称:国家自然科学基金委青年基金—“p-n型吸附-催化剂研制及其非均相催化净水机理”;项目编号:51008292;起止时间:2011/01-2013/12
7. 项目名称:水重大专项子课题—“郊区黄浦江水源臭氧生物活性炭深度处理工艺关键技术研究”;项目编号:2012zx07403-002-02;起止时间:2012/08-2015/12
8. 项目名称:国家自然科学基金重点基金子课题—“城市污水厂除磷及其资源化技术研究”;项目编号:51138009;起止时间:2012.1-2016.12
奖励与荣誉
1. 2021年,项目名称:污酸/污水中重金属资源化与深度处理技术及其应用.环境保护科学技术二等奖;颁发机构:中华人民共和国环境保护部
2. 2018年,第二届青年科学家奖;级别:金奖;颁发机构:中国环境科学学会(个人,全国10人)
3. 2017年,项目名称:功能性吸附微界面构造及深度净水技术.级别:国家技术发明奖二等奖;颁发机构:中华人民共和国科学技术部
4. 2016年,项目名称:辅助电还原/电凝聚及高效多相分离净水技术与应用;级别:环境保护科学技术一等奖;颁发机构:中华人民共和国生态环境部
5. 2015年,项目名称:一种多元复合金属氧化物除砷沉降剂及其应用方法.级别:中国专利优秀奖;国家知识产权局
6. 2014年,项目名称:水中as(iii)和as(v)一步法去除技术及应用.环境保护科学技术一等奖;颁发机构:中华人民共和国环境保护部
学术成果
近5年主要sci论文
1. huachun lan, jing zhou, zhiang hou, xiaoqiangan, huijuan liu, jiuhuiqu. defect modulation of mof-derived znfe2o4/cnts microcages for persulfate activation: enhanced nonradical catalytic oxidation. chemical engineering journal, https://doi.org/10.1016/j.cej.2021.133369
2. yue ran, yuqi cui, yilin zhang, yaoxun fang, wenxuan zhang, xuelian yu, huachun lan, xiaoqiang an*. assembly-synthesis of puff pastry-like g-c3n4/cds heterostructure as s-junctions for efficient photocatalytic water splitting. chemical engineering journal, https://doi.org/10.1016/j.cej.2021.133348
3. jun zhang, gong zhang, huachun lan, jiuhui qu, huijuan liu*. synergetic hydroxyl radical oxidation with atomic hydrogen reduction lowers the organochlorine conversion barrier and potentiates effective contaminant mineralization. environmental science & technology, 2021,55(5):3296-3304.
4. lie liu, kuiling li, shiyu zhao, jianbing wang*, huachun lan, jun wang*. the effects of electrophoresis, bubbles and electroosmosis for conductive membrane performance in the electro-filtration process. journal of membrane science, 2021, 620: 118955.
5. renyuwang, huijuanliu, kaizhang, gongzhang, huachunlan*, jiuhui qu. ni(ii)/ni(iii) redox couple endows ni foam-supported ni2p with excellent capability for direct ammonia oxidation. chemical engineering journal, 2021, 404, 15: 126795.
6. liu, zichen, zhang, gong, lan, huachun, liu, huijuan*, qu, jiuhui. optimization of a hierarchical porous-structured reactor to mitigate mass transport limitations for efficient electrocatalytic ammonia oxidation through a three-electron-transfer pathway. environmental science & technology, 2021, 55(18):12596-12606.
7. zhang, shun, miao, shiyu, an, xiaoqiang, lan, huachun*, liu, ruiping, peng, jianfeng, liu, huijuan, qu, jiuhui. transformation of typical components in anaerobically digested sludge during its conditioning process by kmno4. resources, conservation and recycling,2021,171:105657.<
8. cui, yuqi, an, xiaoqiang, zhang, shun, tang, qingwen, lan, huachun*, liu, huijuan, qu, jiuhui. emerging graphitic carbon nitride-based membranes for water purification.water research, 2021, 200: 117207.
9. huabin zeng, huachun lan*, xiaoqiang an. eveliina repo, yuri park, olga pastushok, huijuan liu, jiuhuiqu. insight into electroreductive activation process of peroxydisulfate for eliminating organic pollution: essential role of atomic hydrogen. chemical engineering journal, 2021, 426: 128355
10. jianfei li, huijuan liu, huachun lan*, qinghua ji, xiaoqiang an, ruiping liu, jiuhui qu. a promising treatment method for cr(vi) detoxification and recovery by coupling fe0/fe3c/c fine powders and circulating fluidized bed. chemical engineering journal, 2020, 398: 125565.
11. shiyu miao, chao jin, ruiping liu*, yaohui bai, huachun lan, huijuan liu, chengzhi hu, jiuhui qu. carbon harvesting from organic liquid wastes for heterotrophic denitrification: feasibility evaluation and cost and emergy optimization. resources, conservation and recycling, 2020, 160: 104782.
12. jing zhou, xiaoqiang an, huachun lan*, huijuan liu, jiuhui qu. new insights into the surface-dependent activity of graphitic felts for the electro-generation of h2o2. applied surface science, 2020, 509:144875.
13. jing zhou, xiaoqiang an*, qingwen tang, huachun lan, qiang chen*, huijuan liu, jiuhui qu. dual channel construction of wo3 photocatalysts by solution plasma for the persulfate-enhanced photodegradation of bisphenol a. applied catalysis b: environmental, 2020, 277: 119221.
14. jun zhang, gong zhang, qinghua ji, huachun lan, jiuhui qu, huijuan liu*. carbon nanodot-modified feocl for photo -assisted fenton reaction featuring synergistic in-situ h2o2 production and activation. applied catalysis b: environmental, 2020, 266: 118665.
15. qingwen tang, xiaoqiang an, jing zhou, huachun lan*, huijuan liu, jiuhui qu. one-step exfoliation of polymeric c3n4 by atmospheric oxygen doping for photocatalytic persulfate activation. journal of colloid and interface science, 2020,579: 455-462.
16. qingwen tang, xiaoqiang an, huachun lan*, huijuan liu, jiuhui qu. polyoxometalates/tio2 photocatalysts with engineered facets for enhanced degradation of bisphenol a through persulfate activation. applied catalysis b: environmental, 2020, 268: 118394.
17. jing qi, huachun lan*, ruiping liu, huijuan liu, jiuhui qu. efficient microcystis aeruginosa removal by moderate photocatalysis-enhanced coagulation with magnetic zn-doped fe3o4 particles. water research, 2020, 171: 115448.
18. junyu zhang, gong zhang, shengyao jin, yujun zhou, qinghua ji*, huachun lan, huijuan liu, jiuhui qu. graphitic n in nitrogen-doped carbon promotes hydrogen peroxide synthesis from electrocatalytic oxygen reduction. carbon, 2020, 163: 154-161.
19. zichen liu, gong zhang, kai zhang, huachun lan, huijuan liu*, jiuhui qu. low electronegativity mn bulk doping intensifies charge storage of ni2p redox shuttle for membrane-free water electrolysis. journal of materials chemistry a, 2020, 8(7): 4073-4082.
20. jun zhang, qinghua ji, huachun lan, gong zhang*, huijuan liu*, jiuhui qu. synchronous reduction-oxidation process for efficient removal of trichloroacetic acid: h* initiates dechlorination and •oh is responsible for removal efficiency. environmental science & technology, 2019, 53(24): 14586-14594
21. jianfei li, huachun lan*, huijuan liu, gong zhang, xiaoqiang an, ruiping liu, jiuhui qu. intercalation of nanosized fe3c in iron/carbon to construct multifunctional interface with reduction, catalysis, corrosion resistance, and immobilization capabilities. acs applied materials & interfaces, 2019, 11, 17: 15709-15717
22. huachun lan, feng wang, mei lan, xiaoqiang an*, huijuan liu, jiuhui qu. hydrogen-bond-mediated self-assembly of carbon-nitride-based photo-fenton-like membranes for wastewater treatment. environmental science & technology, 2019, 53, 12: 6981-6988
23. ning li, chengzhi hu, huachun lan, ruiping liu*, huijuan liu, jiuhui qu. enhanced production of in situ keggin al137 polymer by a combined fe-al coagulation process for the treatment of high alkalinity water. acs sustainable chemistry & engineering, 2019, 7, 10: 9544-9552
24. xiaoqiang an, qingwen tang, huachun lan*, huijuan liu, jiuhui qu. polyoxometalates/tio2 fenton-like photocatalysts with rearranged oxygen vacancies for enhanced synergetic degradation. applied catalysis b: environmental, 2019, 244: 407-413.
25. zhenao gu, xiaoqiang an, huachun lan, yu tian, jinxing zhang, ruiping liu*, huijuan liu, jiuhui qu. microfluidic-enhanced 3-d photoanodes with free interfacial energy barrier for photoelectrochemical applications. applied catalysis b: environmental, 2019, 244: 740-747.
26. tong li, gong zhang*, huachun lan, huijuan liu, jiuhui qu. enhanced photoreduction of chromium(vi) intercalated ion exchange in biobr0.75i0.25 layers structure by bulk charge transfer. acs sustainable chem. eng., 2019, 7 (2): 2429–2436
27. xiaoqiang an, siqi wu, qingwen tang, huachun lan*, yulin tang, huijuan liu, jiuhui qu. strongly coupled polyoxometalates/oxygen doped g-c3n4 nanocomposites as fenton-like catalysts for efficient photodegradation of sulfosalicylic acid. catalysis communications, 2018, 112: 63-67.
28. li yu, gong zhang, chunlei liu, huachun lan, huijuan liu*, jiuhui qu. interface stabilization of undercoordinated iron centers on manganese oxides for nature-inspired peroxide activation. acs catal., 2018, 8 (2): 1090–1096
29. li yu, gong zhang, chunlei liu, huachun lan, huijuan liu*, jiuhui qu. site-specific surface tailoring for metal ion selectivity via under-coordinated structure engineering. nanoscale horizons, 2018, 3(6), 632-639.
30. yanjie wang, huachun lan, lin li*, kaixiong yang, jiuhui qu, junxin liu. chemicals and microbes in bioaerosols from reaction tanks of six wastewater treatment plants: survival factors, generation sources, and mechanisms. scientific reports, 2018, 8(1), 9362.
31. xiaoqiang an, chengzhi hu*, huachun lan, huijuan liu, jiuhui qu. strongly coupled metal oxide/reassembled carbon nitride/co–pi heterostructures for efficient photoelectrochemical water splitting. acs appl. mater. interfaces, 2018, 10 (7): 6424–6432
32. huachun lan, yulin tang, xuehong zhang, shaohong you, qingwen tang, xiaoqiang an, huijuan liu, jiuhui qu. decomplexation of cu(ii)-edta over oxygen-doped g-c3n4: an available resource towards environmental sustainability. chem.eng.j., 2018, 345: 138-146.
33. jianrong li, lei xu, ming-lai fu*, huachun lan*. can adsorbent of layered chalcogenide be regenerated? a case study of norfloxacin adsorbed by layered chalcogenide in water. colloids surf.physicochem.eng.aspects, 2018, 537: 287-293.
34. jing qi, huachun lan, ruiping liu*, huijuan liu, jiuhui qu. fe(ii)-regulated moderate pre-oxidation of microcystis aeruginosa and formation of size-controlled algae flocs for efficient flotation of algae cell and organic matter. water res., 2018, 137: 57-63.
35. ran mao, huachun lan*, li yan, xu zhao, huijuan liu, jiuhui qu. enhanced indirect atomic h* reduction at a hybrid pd/graphene cathode for electrochemical dechlorination under low negative potentials. environmental science: nano, 2018, 5(10), 2282-2292.
36. xing wang, baiwen ma, yaohui bai*, huachun lan, huijuan liu, jiuhui qu. the effects of hydrogen peroxide pre-oxidation on ultrafiltration membrane biofouling alleviation in drinking water treatment. journal of environmental sciences, 2018, 73: 117-126.
37. xing wang, baiwen ma*, yaohui bai, huachun lan, huijuan liu, jiuhui qu. comparison of the effects of aluminum and iron(iii) salts on ultrafiltration membrane biofouling in drinking water treatment. journal of environmental sciences, 2018, 63: 96-104.
38. zhenao gu, le zhang, bo wen, xiaoqiang an, huachun lan, limin liu, tao chen, jing zhang, xingzhong cao, junwang tang, huijuan liu, jiuhui qu*. efficient design principle for interfacial charge separation in hydrogen-intercalated nonstoichiometric oxides. nano energy, 2018, 53: 887-897.
39. xiaoqiang an, huachun lan*, ruiping liu, huijuan liu, jiuhui qu. light absorption modulation of novel fe2tio5 inverse opals for photoelectrochemical water splitting. new journal of chemistry, 2017, 41: 7966
40. huachun lan, lili li, xiaoqiang an*, fei liu, cuibai chen, huijuan liu, jiuhui qu. microstructure of carbon nitride affecting synergetic photocatalytic activity: hydrogen bonds vs. structural defects. applied catalysis b: environmental, 2017, 204: 49-57.
41. huachun lan, lili li, huijuan liu, xiaoqiang an*, fei liu, cuibai chen, jiuhui qu. melem-based derivatives as metal-free photocatalysts for simultaneous reduction of cr(vi) and degradation of 5-sulfosalicylic acid. journal of colloid and interface science, 2017, 507: 162-171.
42. huachun lan, gong zhang, hongwei zhang, huijuan liu, ruiping liu, jiuhui qu. solvothermal synthesis of bioi flower-like microspheres for efficient photocatalytic degradation of bpa under visible light irradiation. catalysis communications, 2017, 98: 9-12.
43. yanzhen liu, ran mao, yating tong, huachun lan*, gong zhang, huijuan liu, jiuhui qu. reductive dechlorination of trichloroacetic acid (tcaa) by electrochemical process over pd-in/al2o3 catalyst. electrochim.acta, 2017, 232: 13-21.
44. baiwen ma, xing wang, ruiping liu*, william a. jefferson, huachun lan, huijuan liu, jiuhui qu. synergistic process using fe hydrolytic flocs and ultrafiltration membrane for enhanced antimony(v) removal. j.membr.sci., 2017, 537: 93-100.
45. baiwen ma, xing wang, ruiping liu*, zenglu qi, william a. jefferson, huachun lan, huijuan liu, jiuhui qu. enhanced antimony(v) removal using synergistic effects of fe hydrolytic flocs and ultrafiltration membrane with sludge discharge evaluation. water res., 2017, 121: 171-177.
46. wenjing sang, gong zhang, huachun lan*, xiaoqiang an, huijuan liu. the effect of different exposed facets on the photoelectrocatalytic degradation of o-chlorophenol using p-type cu2o crystals. electrochim.acta, 2017, 231: 429-436.
47. xiao wang, gong zhang, huachun lan, ruiping liu, huijuan liu*, jiuhui qu. preparation of hollow fe-al binary metal oxyhydroxide for efficient aqueous fluoride removal. colloids surf.physicochem.eng.aspects, 2017, 520: 580-589.
48. zan he, huachun lan*, wenxin gong, ruiping liu, yuping gao, huijuan liu, jiuhui qu. coagulation behaviors of aluminum salts towards fluoride: significance of aluminum speciation and transformation. separation and purification technology, 2016, 165: 137-144.
49. huachun lan, wenjing he, aimin wang, ruiping liu*, huijuan liu, jiuhui qu, c. p. huang. an activated carbon fiber cathode for the degradation of glyphosate in aqueous solutions by the electro-fenton mode: optimal operational conditions and the deposition of iron on cathode on electrode reusability. water res., 2016, 105: 575-582.
50. huachun lan, jianfei li, meng sun, xiaoqiang an, chengzhi hu, ruiping liu, huijuan liu, jiuhui qu*. efficient conversion of dimethylarsinate into arsenic and its simultaneous adsorption removal over fecx/n-doped carbon fiber composite in an electro-fenton process. water res., 2016, 100: 57-64.
51. huachun lan, ran mao, yating tong, yanzhen liu, huijuan liu, xiaoqiang an, ruiping liu*. enhanced electroreductive removal of bromate by a supported pd–in bimetallic catalyst: kinetics and mechanism investigation. environ. sci. technol., 2016, 50 (21): 11872–11878
52. ran mao, ning li, huachun lan, xu zhao, huijuan liu, jiuhui qu*, meng sun. dechlorination of trichloroacetic acid using a noble metal-free graphene–cu foam electrode via direct cathodic reduction and atomic h*. environ. sci. technol., 2016, 50 (7): 3829–3837
53. jing qi, huachun lan*, huijuan liu, ruiping liu, shiyu miao, jiuhui qu. simultaneous surface-adsorbed organic matter desorption and cell integrity maintenance by moderate prechlorination to enhance microcystis aeruginosa removal in kmno4-fe(ii) process. water res., 2016, 105: 551-558.
54. jing qi, huachun lan, ruiping liu, shiyu miao, huijuan liu*, jiuhui qu. prechlorination of algae-laden water: the effects of transportation time on cell integrity, algal organic matter release, and chlorinated disinfection byproduct formation. water res., 2016, 102: 221-228.
55. jing qi, huachun lan, shiyu miao, qiang xu, ruiping liu, huijuan liu*, jiuhui qu. kmno4–fe(ii) pretreatment to enhance microcystis aeruginosa removal by aluminum coagulation: does it work after long distance transportation? water res., 2016, 88: 127-134.
56. huachun lan, xiaobin liu, huijuan liu, ruiping liu, chengzhi hu, jiuhui qu*. efficient nitrate reduction in a fluidized electrochemical reactor promoted by pd–sn/ac particles. catalysis letters, 2016, 146: 91–99.
57. wang sida,lan huachun,liu huijuan*, qu jiuhui. fabrication of feooh hollow microboxes for purification of heavy metal-contaminated water. physical chemistry chemical physics, 2016, 18(14): 9437-9445
58. yu li, liu huijuan*, liu chunlei, lan huachun, qu jiuhui. magnetically-confined fe-mn bimetallic oxide encapsulation as an efficient and recoverable adsorbent for arsenic(iii) removal. particle & particle systems characterization, 2016, 33(6): 323-331
59. qi zenglu, lan huachun,tista prasai joshi, liu ruiping* , liu huijuan, qu jiuhui. enhanced oxidative and adsorptive capability towards antimony by copper-doping into magnetite magnetic particles. rsc advances, 2016, 6(71): 66990-67001
60. jia-cheng e. yang, huachun lan, xiao-qiong lin, baoling yuan, ming-lai fu. synthetic conditions-regulated catalytic oxone efficacy of mnox/sba-15 towards butyl paraben (bpb) removal under heterogeneous conditions. chem.eng.j., 2016, 289: 296-305.
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